Synthesis of silver nanoparticles from Indian red yeast rice and its inhibition of biofilm in copper metal in cooling water environment.

The development of environmentally acceptable benign techniques using purely natural methods is a cost-effective procedure with long-term benefits in all areas. With this consideration, myco synthesized silver nano particles (AgNPs) were studied and it acted as an impending corrosion inhibitor in the environment. Initially, AgNPs were evaluated by physical and surface characterizations and this evidence demonstrated that RYRE's water-soluble molecules played an essential role in the synthesis of AgNPs in nano spherical size. The myco synthesized of AgNPs has showed an antibacterial activity against corrosive bacteria in cooling water system (CWS). Hence, the AgNPs were used in biocorrosion studies as an anticorrosive agent along with AgNO3 and RYRE was also checked. For this experiment, the copper (Cu) metal (CW024) which is commonly used was selected, the result of corrosion rate was decreased, and inhibition efficiency (82%) was higher in the presence of AgNPs in system IV. Even though, AgNO3 and RYRE had contributed significant inhibition efficiency on Cu at 47% and 61%, respectively. According to XRD, the reaction of AgNPs on Cu metal resulted in the formation of a protective coating of Fe2O3 against corrosion. EIS data also indicated that it could reduce the corrosion on the Cu metal surface. All of these findings point out the possibility that the myco-synthesized AgNPs were an effective copper metal corrosion inhibitor. As a result, we encourage the development of myco-synthesized AgNPs, which could be useful in the industrial settings.

Macrolepiota-mediated synthesized silver nanoparticles as a green corrosive inhibitor for mild steel in re-circulating cooling water system.

A simple, cost effective and eco-friendly silver nanoparticle (AgNPs) was synthesized by wild edible Macrolepiota mushroom. Nanoparticles were characterized by UV-visible, FTIR, XRD analysis and TEM analysis. The characterized studies confirmed the spherical shape of AgNPs with 20-50 nm size. Biocorrosion efficacy of myco-synthesized AgNPs and the mushroom extract were tested against mild steel by corrosive bacteria Bacillus thuringiensis EN2, Terribacillus aidingensis EN3 and Bacillus oleronius EN9. Weight loss analysis, EIS, and surface analysis were used to evaluate the corrosion inhibition efficiency of mild steel in various experimental systems. Reduced corrosion rate (0.07 mm/y, 0.14 mm/y), reduced weight loss (0.006 ± 2, 0.011 ± 2) and increased corrosion inhibition efficiency (59%, 18%) were identified in both system II and system IV. Peak intensity was reduced in both surface analysis studies (FTIR and XRD) in the presence of mushroom extract and AgNPs. EIS studies reveal that the mushroom extract and AgNPs act as a corrosive green inhibitor and adsorbs on the mild steel surfaces in cooling water tower system, which are responsible for corrosion protection.